The aluminum dissolution increased by incorporating thermal treatment from 5 to 80% in muffle and % in microwave routes. The acidbase precipitation process resulted in the recovery of ~ 98% dissolved aluminum values in the boehmite phase, leaving the solution with less than 50 ppm Al content suitable for leaching application.
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Primary aluminum production is achieved by the combination of two metallurgical processes: (a) the Bayer process, which refines bauxite to metallurgicalgrade alumina (MGAl 2 O 3), and (b) the HallHéroult process, which produces aluminum metal by electrolytically reducing MGAl 2 O 3 in a cryolite bath. Increasing the sustainability of both these processes and of the entire primary ...
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Bauxite residue (red mud) is an alkaline waste derived from the industrial process for extraction of alumina from bauxite ore. Some bauxite residues contain considerable concentrations of critical metals, for example, rare earth elements. Lithium in red mud was also reported as a potential resource. In the current study, a Lirich red mud was leached using acetic acid to investigate the ...
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In this study, extraction of aluminum, iron, and titaniumbearing constituents from diasporetype bauxite ores was investigated by stepwise treatment consisting of predesilication via alkalileaching of bauxite ore, extraction of alumina via Bayer process, and recovery of iron from red mud via magnetic separation. The predesilication results showed that the removal of silica reached % ...
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Red mud is a kind of strong alkaline hazardous slag discharged from aluminum metallurgy industry. In this study, the water immersion with high temperature and high pressure was developed for the selective dealkalization from red mud by adding Mgbased additives. The removal efficiency of alkali could reach 92% by using 12% MgCl2 with 9 mL/g at 250 °C for 60 min. The MgCl2 was the most ...
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As a hybrid process, bauxite residue undergoes a reductive smelting process with lime addition in an electric arc furnace in order to generate aluminaenriched slag. This slag is subsequently treated with highpressure caustic leaching at moderated (200300 g/l) and high (572762 g/l) sodium hydroxide concentrations.
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This paper describes a novel process, hematite involved roasting − alkaline leaching − Bayer digestion, to extract silica and alumina from highalumina coal gangue (HACG). The phase transformations during roasting were investigated through Xray diffraction, Xray photoelectron spectroscopy, scanning electronic microscope, and energydispersive spectrometer. The silica and alumina ...
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The major commercial technology for the production of smelter grade alumina has conventionally been the Bayer process which converts bauxite ore, an aluminum containing ore which typically contains about 50 % Al 2 O 3, into smelter grade alumina that contains over % Al 2 O potential source of aluminum that is receiving renewed attention is coal fly ash (CFA), which is a by ...
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In the Bayer's process of extracting alumina from bauxite using caustic soda, the waste generated is called as red mud/bauxite residue. About tonne of bauxite residue is generated per tonne of alumina produced depending upon the bauxite and process conditions used. It is generally stockpiled into the red mud ponds situated near the industrial area and is highly alkaline which is a ...
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The Bayer process is currently used to produce cellgrade alumina from bauxite. However, if the reactive silica content in the bauxite exceeds 7%, losses of caustic and aluminium as sodalite (2 Na 2 Al 2 O 3 ·3 SiO 2 ·2 H 2 O) become economically unacceptable. As Australia possesses large tonnages of bauxite containing more than 7% ...
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Experimental Method. In this study, the recovery of precious metals from bauxite ore was examined by a twostage leaching process. The stages of this process were Stage I: Removing iron to a large extent and revealing the solubility conditions of titanium by treating the bauxite ore with oxalic acid, Stage II: Determining the recovery conditions of aluminum from the residue obtained after the ...
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Bauxite is widely used to produce alumina. There are many bauxite resources with high iron content. These resources could not be processed and utilized efficiently due to the high concentration of iron (Fe). The alkaline leaching process has been proposed to remove iron from these bauxite resources. Therefore, in this study, the alkaline leaching process was employed, and the effects of sodium ...
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Gibbsitic bauxite from Australia was leached by hydrochloric acid in this work. Analysis on kinetics for the extraction of Al 2 O 3 was quantitatively studied. It was concluded that the hydrochloric acid leaching process of gibbsitic bauxite was controlled by chemical reaction. Moreover, the mechanism for the dissolution followed the equation ...
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In the leaching of Alumina from bauxite, concentration of the ore is done by digesting the powdered ore with N aOH and then it is later reacted with CO2 gas. Consider the major impurities presents related to them. I. SiO2 is leached out along with Al2O3 as silicate and aluminate on reaction with N aOH. II.
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direct acid leaching are the consumption of large amounts of acid for neutralization, the handling of large volumes of effluents, and the difficulty in using the bauxite residue after leaching. Recovery of iron prior to leaching can improve the economics of the process. However, high alumina in the bauxite residue increases the flux and acid
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Leaching Process Examples. The leaching process example includes the leaching of bauxite or Al2O3 . 2H₂O with the concentrated and heated sodium hydroxide. The concentrated NaOH here tends to dissolve the aluminium present in the given bauxite, while on the other hand, the impurities like SiO2, TiO2, and Fe2O3 do not get dissolved.
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Abstract The recovery of major components of bauxite residue by carbothermic reduction at °C and subsequent slag leaching in a Na3CO3(aq) solution is studied. Iron recovers primarily to pigiron and lime is added to tune the calcium aluminate slags towards the highly leachable mayenite phase. The concentration of aluminum in the leachate correlates well with the occurrence of ...
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In the water leaching process, Na Al Si O 4 was dissolved while the amorphous phase underwent some transformations to form the water leaching residue, ... When highsilica bauxite is used as a feedstock for alumina production, more bauxite residue is discharged compared to processing highgrade bauxite. 30 At present, ...
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The generation of bauxite residue during the production of alumina from bauxite ore is considered as one of the major concerns of alumina refineries throughout the world. In Bayer process after digestion of the bauxite ore in hot caustic solution, the bauxite residue is separated, washed, and disposed dry or in a pond.
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The global bauxite market is projected to reach US billion by 2030, at a CAGR of %. Production of bauxite is concentrated in a few countries, with Australia, China, and Guinea being the ...
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The solution is clarified by filtering off the solid impurities, commonly with a rotary sand trap and with the aid of a flocculant such as starch, to remove the fine particles. The undissolved waste after the aluminium compounds are extracted, bauxite tailings, contains iron oxides, silica, calcia, titania and some unreacted alumina.
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Aluminum, which has the outstanding advantages of light weight and corrosion resistance, has a wide range of use in industries including aircraft, construction, automobile, and so on [].Unlike the iron direct extraction from iron ore, pure powder alumina should be firstly extracted from bauxite by alkali methods (Bayer process and sintering process), and then aluminum is produced through ...
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Roasting and Leaching. Kaolin was roasted at 850 °C for 2 h in a muffle furnace. The sample was placed in an alumina crucible and kept inside the chamber, and the temperature was maintained at 850 °C in the fivestage program. The roasted Kaolin was leached in HCl and H 2 SO 4 to liberate alumina.
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During the digestion process of the Bayer method, lithium and gallium in bauxite will enter into the sodium aluminate solution (Tang et al. 2020; Xu et al. 2018 ), which will return to the digestion process for recycling after the precipitation of aluminum hydroxide from the decomposition of crystal species.
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Hall's process for leaching of alumina from bauxite: (1) Bauxite ore and sodium carbonate are fused toghether to convert aluminium oxide into soluble sodium metaaluminate. The insoluble residue contains the impurities of silica and iron oxide. The fused mass is treated with water.
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Both forms can have deleterious effects on Bayer process operations used to produce smelter grade alumina from bauxite ore. Jamaican bauxite which is comprised mainly of gibbsite (Al 2 O 3 ·3H 2 ...
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Leaching of alumina from bauxite: The process has been successfully applied in the case of bauxite ( (Al_2O__2O)), an ore of aluminium associated with the impurities of iron oxide ((Fe_2O_3)), titanium oxide ((TiO_2)) and sand ((SiO_2)). The powdered ore is leached with concentrated NaOH solution at 473 523 K temperature and 35 ...
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A material supplier from Belgium would like to produce limestone powder for his custome...
India is rich in various mineral resources and it is an important mineral processing market
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